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Total Synthesis of Transtaganolide E and F: Insight in the Biosynthesis of the Transtaganolides

Author:
  • Rikard Larsson
  • Hans W. Scheeren
  • Rene W. M. Aben
  • Martin H Johansson
  • Olov Sterner
Publishing year: 2013
Language: English
Pages: 6955-6960
Publication/Series: European Journal of Organic Chemistry
Volume: 2013
Issue: 30
Document type: Journal article
Publisher: John Wiley & Sons

Abstract english

A total synthesis of transtaganolide E and F, proposed intermediates in the biosynthesis of the potent transtaganolides, including an Ireland-Claisen rearrangement and a high-pressure intramolecular Diels-Alder cycloaddition reaction of an unactivated 2-pyrone derivative, is reported. The implication of the results to the proposed transtaganolides biosynthesis is discussed.

Keywords

  • Chemical Sciences
  • Transtaganolides
  • Rearrangement
  • Cycloaddition
  • Biosynthesis
  • Natural
  • products

Other

Published
  • ISSN: 1434-193X
Olov Sterner
E-mail: olov [dot] sterner [at] science [dot] lu [dot] se

Dean

Faculty of Science

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Professor

Centre for Analysis and Synthesis

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